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Reactions of Sm(OC_6H_2t~Bu_2-2,6-Me-4)_3(THF)_2 with AgBPh4 gave cationic trivalent product (ArO)_2Sm(DME)_2.BPh4 6 which was characterized by elemental analysis, IR spectroscopy, 1H NMR spectroscopy and X-ray diffraction.

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