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PFMnC-Br was used as macroinitiator to initiate the ATRP of t-butylmethacrylate(t-BMA), thus PFMnC-b-P(t-BMA) with narrow distribution was obtained. After hydrolyzationand acidition, the amphiphilic diblock copolymers PFMnC-b-PMAA was prepared.

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