New calix\arene poly(aza) derivatives 3,4 and bis-calix\arene 5 containing azo-groups,amido groups and Schiff-base groups were synthesized in yields of 87%,89%,84%,respectively.

• 合成了含有偶氮基、胺基、酰胺基和席夫碱基新型杯[4]芳烃多重氮杂衍生物3和4以及双杯[4]芳烃5,产率分别为87%25、89%25和84%25。