Lead dioxide may also be prepared by the hydrolysis of lead[IV] salts; for example, lead tetrachloride may be hydrolyzed in cold hydrochloric acid solution, or a saturated solution of lead tetraacetate may be hydrolyzed in glacial acetic acid.

• pbO2还可以通过水解四价铅盐的方法来制备,例如,pbCl4可以在冷的盐酸溶液中水解；而pb(OAc)4的饱和溶液可以在冰醋酸中水解。